Puerto la Cruz
Puerto la Cruz is a city in Venezuela.
Who knows, maybe you'll end up here after hitching sailing boats across the ocean :)
West towards Caracas
Take a bus in the direction Barcelona. Ask if they go to Redoma los Pajaros, which is a big roundabout at the city limits, with a gas station right before it and another right after. There is a PDV gas station 1 km futher. Walk or get a ride there. It's the last and the busiest gas station. It is easy to get a ride straight to Caracas.