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You have two solutions for these destinations. First is to get the bus on one of the main bus terminals in Zagreb. The name of that terminal is Kvatrić or Kvaternikov Trg (square), its near center of Zagreb. Then you have to get on bus number 216 and 276 which rides you to Ivanja Reka or the main ramp on the highway. Of course ask the bus driver to leave you in Ivanja Reka and after that you have 20 min of walk through some fields. But dont worry, its a delightful walk haha. After you reach the ramp you can easy get rides directly to border with Serbia, Belgrade and the border with Bosnia. Second solution is to get the tram number 2, 3 and 13 to Savišće or Žitnjak. On the last stop come down and then walk for about 15 min to the highway. On the highway is a bus stop sign and there you can easy hitchhike to ramp in Ivanja Reka or you can even stop cars who are going to Belgrade and Bosnia. Ask the locals for extra tips and explanations... nuclearphyllis' local experts took us to the first toll plaza on the zagreb-belgrade highway, even though it was illegal to hitchhike from there. we weren't troubled and got a ride in under 10 minutes.